Papa Kiʻi no kēiaʻatikala:
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2.ʻO nā waiwai hoʻolālā
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4.ОО pauhu
5. Synthesis
6.ʻO nā waiwai olakino
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8..ʻO ka hana Antimicrobial
9.ʻO nā waiwai Rheological
10.ʻO nā noi i nāʻoihana cosmetic
11. Nā noi noi i nā lāʻelua
Nā meaʻala amino acd (Aas)he papa o nā mea e hanaʻia e ka hoʻohuiʻana i nā hui hydrophobic me hoʻokahi a iʻole nā amino amino. I kēia hihia, hiki i nā Achids Amino ke synthetic a iʻole i loaʻa mai nā hydrolys i loaʻa a iʻole nā kumuwaiwai hou. Hoʻopili kēia pepa i nā kiko'ī o ka hapa nui o nā ala synthetic i loaʻa no AAS a me ka hopena o nā alaloa o nā huahana i pau E like me ka papa o nā mea hana i ka hoʻonuiʻana i ka noi, keʻano o ka atas ma muli o ko lākouʻano hoʻohālikelike he nui o nā manawa kūpono.
Hāʻawiʻia nā mea hana e hoʻohana nuiʻia i nā mea kanu, nā emulsifiers, nā mea hana inohi,ʻaʻole i pau nā mea kūʻai aku i nā mea kūʻai aku.
ʻO nā kumuwaiwai nā mea nui loa e hoʻopau i nā huahana nui i hoʻopauʻia ma ka nui o nā lā ma kahi o ka honua a loaʻa i kahi hopena maikaʻi loa ma ka wahi aquatic ma ke kaiāulu.Ua hōʻikeʻia nā haʻawina e hoʻohana ana i ka hoʻohanaʻana i nā mea hana maʻamau i hiki ke loaʻa i kahi hopena maikaʻiʻole i ke kaiapuni.
I kēia lā,ʻaʻole i like me ka Biodegratability a me Biodegratability a kokoke i ka mea nui e like me ka mea nui e like me ka hana a me nā hana o nā mea hana.
ʻO nā mea pili aloha e pili ana i nā mea he mau mea e pili ana i nā mea iʻike nuiʻia e nā microorganisms e like me ka baictteriaNo laila, hiki iāʻoe ke hoʻomākaukauʻia nā bioriffants e hoʻomākaukauʻia e Moolecular i nā hana amphiphilic, e like me phospholidids a me nā phospholidipids a me nā phosphides a me nā phospholididids a me nā phospholididids a me nā phosphides a me nā phospholidids a acyll
Nā meaʻala amino acd (Aas)ʻo ia kekahi o nā mea hana maʻamau, maʻamau i hanaʻia mai nā holoholona holoholona a iʻole nā mea mahiʻai i loaʻa i nā mea hana. Ma nā makahikiʻelua i hala aku nei, ua likeʻo Aas i ka makemake nui o nāʻepekema,ʻaʻole wale no ka wikiwiki, akā pono wale nō ka mea e mālamaʻole ai iā ia.
AAS can be defined as a class of surfactants consisting of Amino Acids containing Amino Acid groups (HO 2 C-CHR-NH 2) or Amino Acid residues (HO 2 C-CHR-NH-). ʻO nā papa hana 2 o nā wahi o Amino Acids eʻae i ka hoʻouluʻana o nāʻano ākea. ʻO ka huina o 20 mau o nā amino cradion aminogenic eʻikeʻia e noho i keʻano a ke kuleana no nā hana olakino a me nā hana ola. ʻOkoʻa lākou i kēlā me kēia i kēlā me kēia e like me ke koena R (kiʻi 1, pk a ka mea maikaʻiʻole o ka hoʻonāʻana o ka hopena). ʻO kekahi mau polar a me nā hydrophobic, he polar a me nā hydrophilic, he mea maʻamau kekahi a he acidic.
No ka mea,ʻoʻAmelikaʻAmelika e hoʻohui hou i nā mea hoʻohui, e haʻiʻia ana nā mea kanu mai nā amino e pili ana i nā amino e lilo i mea kiʻekiʻe e lilo i mea kūpono a me keʻano kaiāulu. ʻO keʻano maʻalahi a me keʻano kūlohelohe a me keʻano haʻahaʻa a me ka biodegradabeability a me ka rapid biodegradabeability e hana pinepine iā lākou i nā mea maikaʻi loa. Ke hoʻohana nei i nā mea hou hou (eg amino acid acid a me nā ailaʻaila)
I ka makahiki 20 o ka makahiki 20, ua loaʻa muaʻo Amino Acids e hoʻohanaʻia e like me nā mea i kohoʻia no ka synthesis o nā mea kanu.Ua hoʻohana nuiʻiaʻo AAS e like me ka preservatives i loko o nā hana lāʻau lapaʻau a me nā hana cosmetic.ʻO ka hoʻohuiʻia,ʻikeʻiaʻo AAS e pili ana i ka ikaika o ka maʻi o nā maʻi e hōʻeha nei i nā mea maʻi, nā meaʻala, a me nā maʻi. I ka makahiki 1988, ka loaʻaʻana o ka loaʻa kālā haʻahaʻa A AAS i hana i ka noiʻi noiʻiʻana i ka hana. I kēia lā, me ka hoʻomohalaʻana o nā biotechnology, nā mea amino e hiki ke hoʻohuihuiʻia nā mea kūʻai aku ma kahi ākea nui.
01 Kahakai o nalino Agids
E like me ka manawa mua o ka kenekulia 19, i ka manawa iʻike muaʻia ai koʻAmelikaʻAmelika, ua wānana ka waiwai nui - Hoʻohanaʻia lākou e like me ka hoʻomākaukauʻana i nā hana. ʻO ke aʻo muaʻana ma luna o ka synthesis o Aas i hōʻikeʻia e Bondsi i 1909.
I kēlā noiʻi,ʻo n-Ayylglycine a me N-Acylalane Ua pili i ka hana ma hope o ka synthesis o ka synthesis of lipoimino acpids (Aas) me ka hoʻohanaʻana iā Glycine a me Alaline, a hentrich et al. Kauʻia i kahiʻano o nā loaʻa,komo me ka noi mua mua loa, ma ka hoʻohanaʻana i ka Acyl Sarcosinate a me ka Actyl Aspartate i nā mea e hoʻomaʻemaʻe i nā huahanaMa hope aku, ua nīnau pinepineʻia nā poʻe noiʻi he nui a me keʻano o ka Synthesis a me nā mea pono o Styletichamical a me nā maʻi lapaʻau o Aciditsʻo Acidids. I kēia manawa, ua paʻiʻia kahi kino nui o ka puke ma luna o ka synthesis, nā waiwai, nā waiwai, nā noi moʻomeheu a me ka biodegrabile o Atas.
02 Pūnaewele Pūnaewele
ʻO nā kaula momona hydrophobic bartrophobic bardid acans o Asas e loli paha i keʻano, clein lōʻihi a me ka nui.ʻO ka hanaʻokoʻa a me nā hana kiʻekiʻe o Asas e wehewehe i ko lākou mau'āina ākea ākea ākea a me nā waiwai pilikino. ʻO nā pūʻulu poʻo o AAS e huiʻia ana i nā amino amino a iʻole peptides. ʻO nāʻokoʻa i loko o nā hui poʻo e hoʻoholo i ka adsorption, Aggregation a me ka hana hoʻoikaikaʻana o kēia mau mea hana. Nā mokuna hana hana ma ke poʻo o ke poʻo a laila e manaʻoʻo keʻano o Aa; me Cationic, a me Ghomopec, a me'Amenicic, a meʻAmelika. ʻO ka hui pūʻana o nā Amino Amino Amino Acids a me Hydrophobic lōʻihi e hana ana i kahi hoʻolālā amphipolac Eia kekahi,ʻo ke alo o nā carbon carbon atom e kōkua ai i ka molena e kōkua i nā molele chiral.
03 Hoʻomaʻamaʻa Pāʻani Hoʻohana
ʻO nā peptides a me nā polyperptidesʻo nā huahana polymerization o kēia mau mea ma kahi o 20 mau ame-sperinogenic α-biteinogenic α-rivinogenic α-amorinogenic α-galani. Loaʻa i nā amanika 20 α-amino e loaʻa i kahi huiʻoihana hana carboxylic (-cooh) a me kahi hui amino. Maʻalahiʻo Amino Accids mai kekahi i nā hui likeʻole i hoʻopiliʻia e pili ana i ka α-carbon (keʻano o nā hui ʻO kēia mauʻokoʻa e hoʻoholo ai i ka nohona o nā Amino Amino Acids i ka wai.
ʻO nā Amino Agids Amine Heʻelua mau huiʻo Amano ʻO lākou nā kiʻi aniani non-undlapping i nā kiʻi o kēlā me kēia,ʻoiaiʻo ka manaʻo o ka nui o ka l-stereoromomers he kiʻekiʻe loa. ʻO ka R-hui i hōʻikeʻia i kekahi mau amino Acids ʻO ka Acidic α-cooth a me ka mea maʻamau α-nh 2 i nā amino e pili ana i ka inoa inoa, a me nā mea kanuʻelua
R-calh ↔r-co-+ H+
R-nh3+↔R-nh2+ H+
E like me ka hōʻikeʻana ma ka Inization equilibrium ma luna, aia nā hui amino e pili ana i nā hui acid acid iʻelua; Eia nō naʻe, he nui nā hui carboxyl i hoʻohālikelikeʻia i ka hui amino amino. PH 7.4, ua hoʻokaʻawaleʻia ka hui o ka carbyll i ka wā i manaʻoʻia ai ka hui Amano. ʻO nā hui amino Acino-ion-inizable r mau hui me ke kūloheloheʻole ma kēia ph a me keʻano zwitterion.
04 KA LOA
Hiki ke heluʻiaʻo AAs e like me nā kūlanaʻehā, i hōʻikeʻia ma lalo nei i lalo.
4.1 E like me ke kumu
| E like me ka mea i hoʻomaka ai, hiki ke hoʻokaʻawaleʻia AAS i 2 mau māhele e like me kēia. ① nāhelehele kūlohelohe ʻO kekahi mau mea hoʻohālikelike maoli e loaʻa ana i nā amino e loaʻa ana i ka hiki ke hōʻemi i ka paepae / internacial thinsion, aʻoi aku ka nui o ka hopena o nā glycolipids. Ua hoʻokumuʻiaʻia kēia mauas he mau lipoppedes. ʻO nā lipopoptides he haʻahaʻa haʻahaʻa haʻahaʻa haʻahaʻa haʻahaʻa, maʻamau pinepineʻia e nāʻano bacillus.
Ua hoʻokaʻawaleʻia kēlā mau AAS i nā subclasses 3:ʻO Surfin, itoun lāuaʻo Fengycin.
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| ʻO kaʻohana o ka papa-hana ikaika i nā mea e hoʻopuni ana i nā mea hoʻohālikelike heptapeptide o nāʻano likeʻole o nā mea likeʻole.E like me ka hōʻikeʻana ma ke kiʻi 2a, i loko o kahi c12-c16ʻaʻole i hoʻopiliʻiaʻo Β ʻO ka peptide-hana ikaika ka peptide ka hana macrocyclic i paniʻia e ke apo i paniʻia e ka chelyis ma waena o ka c-termixy momona momona a me ka peptide. Ma ka subclass o Itoun, heʻeono mauʻano nui,ʻo ia ka inoa nui,ʻo ia nō he a me cI nā hihia a pau, e hoʻopiliʻia nā'ōmole i nā kaula c14 I ka hihia o nā ekurimincins, hiki i ka hui amino i ke kūlana β-kūlana hiki ke hana i kahi paʻa o ka c-derminanus i ka hana macrocyclic.
ʻO ka subclass i loaʻa i ka fengycin i loaʻa i ka fengycin a a b, i kapaʻiaʻo plitastatin i ka wā e hoʻonohonohoʻia aiʻo Tyr9.Hoʻopiliʻia ka Decaperptide i kahi C14 -C18 Saturated Sturated a iʻole a iʻoleʻole iʻole β-hydroxy momona momona momona momona. Hoʻonohonoho,ʻo ka plupsastatin kekahi mea macrocyclic lactone, i loaʻa i kahi kaulahao ma keʻano he nui o ka c-subinal.
② Kamāliʻina Synthetic Hiki i nā Aas ke kiʻiʻia e ka hoʻohanaʻana i kekahi o nā acidic HoʻohanaʻoʻAmelika Nui no nā synthesis o Asas he glutamic acid, sinecine,ʻo Andirine,ʻo Adanen, a me Adanen hydroeys. Hiki ke hoʻomākaukauʻia kēiaʻano hana o nā mea hana e ka lāʻau lapaʻau, elimala, a me nā chemoengymatika; Eia nō naʻe, no ka hanaʻana o Aas,ʻoi aku ka nui o ka synthenical centhesis. Hoʻokomoʻia nā hiʻohiʻona maʻamau i nā N-Lauroyl-L-Glutamic AcID a me N-Palmitooyl-L-Glutamic ACID.
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4.2 e pili ana i nā mea i huiʻia
E pili ana i nā chin China Altiphatic, hiki ke hoʻokaʻawaleʻia nā mea hana amid Acid-pili i nāʻano i hiki ke hoʻokaʻawaleʻia i loko o 2 mauʻano.
E like me ke kūlana o ka subsituen
| ①n-substitted AAS I nā hui pūʻana o N-subsitinud, ua hoʻololiʻia kahi pūʻulu ammino e kahi hui lipophilic a iʻole kahi hui carboxyl. ʻO ka hiʻohiʻona maʻalahi loa o N-substitted AASʻo N-Acyl Amino Acids,ʻo ia nō nā mea heionatic Ationic. ʻO nā mea i hoʻopiliʻiaʻo N-Spextidted AAS i hoʻopiliʻia ma waena o nā wahi hydrophobic a me nā'āpana hydrophobic a me nā'āpana hydrophilic. ʻO ka pilinaʻo Abide ka hiki ke hana i kahi paʻa hydrogen, e hoʻomaʻamaʻa i ka degradation o kēia mea hana, no laila e hana ana iā ia he biodicadoable.
②c-substidted AAS I loko o nā c-stidetinud compounds, keʻano o ke ala i keʻano o ka hui carboxyl (ma o kahi paʻa a iʻole nā hoa aloha a iʻole estide bond). ʻO nā hui like c-stictituded c-stixtinuted (e like me nā esters a iʻole nā amodes) i nā mea kanu cacants cacants cacants.
③n- a c-spedtitted AAS Ma kēiaʻanoʻano hana,ʻo lāua a me nā hui amino a me nā carboxyl i nā'āpana hydrophilic. ʻO kēiaʻano keʻano heʻano he nui o ka amphteric. |
4.3 Wahi a ka helu o nā huelo hydrophobic
Wahi a nā helu o nā pūʻulu poʻo a me nā huelo hydrophobile, hiki ke hoʻokaʻawaleʻia nā asa iʻehā mau pūʻulu. Nā Kūlana Kūhelu pololei, Gemini (DIMIni) Type AAS, Glychupid Type Aas, a me Bola) Type Aas. ʻO nā mea hoʻokūkū pololei i nā mea e pili ana i nā mea e pili ana i nā amino e pili ana i nā amino e pili ana me hoʻokahi mea hoʻokahi hydrophobic (kiʻi 3). ʻO Gemini Type AAS i loaʻa iʻelua mau pūʻuluʻo Abid Acid Polar Polar a me nā'āpana hydrophobicʻelua no ka molena (kiʻi 4). I kēiaʻano kauoha a me kēiaʻano hoʻonohonohoʻana i pili ai i kahi'āpanaʻeluaʻelua, ua hoʻopiliʻia e ka Supper a he kapa no hoʻi iaʻo DIMERS. Ma keʻanoʻo Glyceroipid eas, ma kaʻaoʻao'ē aʻe, e hoʻopiliʻia nā'āpana hydrophobicʻelua i ka hui like amino Amido. Hiki ke noʻonoʻoʻia kēia mau mea e like me nā annacygs o nā monoglyrieded
4.4 E like me keʻano o ke poʻo poʻo
①ctionation aas
ʻO ke poʻo o ke poʻo o kēiaʻano o kēiaʻano hana he uku maikaʻi. ʻO ke cicalist mua loaʻo Aasʻo Abtyl Cocoyl Sociki ʻO nā mea kūʻokoʻa a me nā mea hana o kēia mea hana e hana ai i mea ponoʻole, nā mea antimicrobial, a me kaʻoluʻolu a me kaʻoluʻolu Singare a me nā mea hoʻokūkū hoʻokūkūʻo Arnik Ma kēia noiʻi, ua haʻi lākou i nā hua kiʻekiʻe o nā huahana i loaʻa i nā kūlana kula. Me ka hoʻonuiʻana i ka lōʻihi o Alkyl Chain a me hydrohobicity, ua loaʻa ka hana o ka papa ʻO kekahi mea'ē aʻe o ka pale a Actynary Acyl
②TIINAIC AAS
Ma nā mea kanu anionic,ʻo ke poʻo poʻo poʻo o ke poʻo o ka papa o ka mea hana he uku maikaʻiʻole. Sarcosine (Ch 3 -nh-ch 2 -coh -COHH,) He mea e pili ana i ka glycine,ʻo ia kahi amino amino amid amid amid i loaʻa i nā cell mammalia. Laurie Acid, teradeac acicac acid, acid acid a me ko lākou mau holoi a me ko lākou mau mea holoi i hoʻohana pinepineʻia e hoʻopili i nā mea kanu sarcosinate. ʻO nā sarcosinates i nā leʻaleʻa aʻo ia hoʻi ka mea maʻamau i hoʻohana pinepineʻia i loko o nā mea hoʻopunipuni, shampoos, eʻoki ana i nā mea hoʻomaʻemaʻe, a me nā mea akamai.
Loaʻa i nā mea kūʻai aku'ē aʻe i loaʻa i nā AASIC AMAS AMASOFT CS-22 a me Amilitegck-12,ʻo ia nā inoa kālepa no Sodium N-cocyll Ua hoʻohana pinepineʻiaʻo'Amitite ma keʻano he mea e neʻe nei, nā pale, nā mea kanu, nā mea kanu holoi, a me nā mea kanu, nā mea kanu holoi, nā mea kanu lole Hoʻohanaʻiaʻo Amisoft ma kahi o kaʻili a me ka hoʻomaʻemaʻeʻana i ka lauoho, nui loa, nā mea hoʻomaʻemaʻe kino, nā hale mālama maka maka, nā hale mālama kino.
③zwitterionic a iʻole amporteric Aas
Loaʻa nā mea a Amphotteric i nā wahi acidic a me nā pūnaewele a hiki ke hoʻololi i kā lākou uku ma o ka hoʻololiʻana i ka waiwai ph. I ka alkaline media e like me nā mea e like me nā mea hana anionic,ʻoiai i nā wahi acidic a lākou e like me nā mea e like me nā mea kanu giatial. ʻO Lauryl Lysine Ll kahi huahana condensation o Lyine a me Laric acid. Ma muli o kānaʻano ghostibic, e like me nā mea āpau e like me nāʻano āpau, koe wale nō no ka alkaline a me nā alkaline a me nā alkaline a me nā alkaline a me nā alkaline a me nā alkaline paha E like me kahi pūpū kūlohelohe, ua maikaʻi loaʻo LL i nā papa he hydropphilic ma Hydropphilic a me kahi haʻahaʻa haʻahaʻa haʻahaʻa Ua hoʻohana nuiʻiaʻo LL i loko o nāʻili a me nā lauoho lauoho, a hoʻohanaʻia hoʻi e like me ka lubricant.
④Ronenioninic Aas
Kuhiʻia nā mea kanu nonionic e nā pūʻulu poʻo polar me nā kumuʻole. ʻEwalu mau mea hou ethoxs i hoʻomākaukauʻia e nā mea indenics i hoʻomākaukauʻia e Al-Sabagh et al. mai nā aʻaʻaila-god-amino. Ma kēia kaʻina hana, L-phenylalanine (lep) a me l-liucine ua manaʻo muaʻia me hexadecoaf i hāʻawiʻia e nā maʻi pākēneka. ʻO nā kiʻi a me nā mea e pili ana i nā mea e pili ana i lalo o nā mea hoʻonaninani me Etelene e hoʻomākaukau ai i nā helu Phenylalanlene e hoʻomākaukau ai i nā helu Phenylalanlene (40, 60 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100 a me 100). Ua loaʻa kēia mau nonoinic Aas e loaʻa i nā waiwai maikaʻi a me nā waiwai.
05 syntheso
5.1ʻO kahi ala synthetic kumu
Ma AAS, hiki ke hoʻopiliʻia nā hui hydrophobic i nā wahi amine a iʻole nā mea i kālaiʻia a iʻole ma o nā kaulahao o Amano. E pili ana i kēia,ʻehā mau ala lāʻauʻelua, e like me ka hōʻikeʻana ma ke kiʻi 5.
Fig.5 Promerash Synthesis i nā ala o Amino Acid-Modents
| Ala 1. Ua hanaʻiaʻo Amphiphilic Eseser Amines e nā hopena estricalification I kekahi mau hana, nā hana acid sulfuric e like me kahi mea catalyst a me kahi luna dehydrating.
Komohana 2. Hoʻokumu i nā Amino Amino Actids e hana ai i nā alfylanes e hana i nā bondud bods
Ala 3. ʻO Abido Abids e syntheszed e ka hanaʻana i nā hui amene o Amino Pladids me Amido Adid.
Ala e 4. ʻO ka lōʻihiʻo Long-Chain Alyl Agids i ka hopena o ka hopena o nā hui amyika me nā halkokan. |
5.2 E holomua i loko o synthesis a me ka hana
5.2.1 synthesis of hoʻokahi chain acino acid / peptide storicants
N-acyl a iʻole o-acyl acid acid acid a iʻole nā peptides e hoʻopiliʻia e ka Aczyme-catalyme-falyme ʻO ka hōʻike mua loa ma ka stovent-free lipease-catalyzed synthesis of amino acid antide a me nā mea hana e pili ana i ka 25% a me 9% a me 90% e like me 9% i ka 90% e pili ana i ka Acticalita. Ua hoʻohanaʻiaʻo Mathyl Etyl Ketone e like me ka mea i loaʻa i kekahi mau hopena. Vosethagen et al. Ua wehewehe pūʻiaʻo Lipase a me Protyase-Catalyzed N-Acylation e Amino Acids a me Trivitylok.
I nā lā mua, ka pilikia nui me ka enzyme-catalyzed synthes o Asas ka haʻahaʻa haʻahaʻa. Mamuli o ka waiwai et al. ʻO ka hāʻawiʻana o ka N-TetradeatLl acid Actid derivatives he 2% -10% ma hope o ka hoʻohanaʻana i nā lipes likeʻole a me ka hoʻopukaʻana ma nā lā he nui. Montot et al. Ua hui pūʻia nā pilikia no ka uku haʻahaʻa o Amino Acids i loko o ka synthesis o ka n-acyl lysine e hoʻohana ana i nā aila momona a me nā ailaʻaila. Wahi a lākou,ʻo ka nui o ka nui o ka huahana he 19% ma lalo o nā kūlana paʻa a me ka hoʻohanaʻana i nā mea hoʻokele organice. ua huiʻia ka pilikia like e ka valivety et al. I loko o ka synthesis o n-cbz-l-l-lysine a iʻole n-cbz-lysine mithyl ester derivatives.
Ma kēia noiʻi, ua'ōlelo lākou he nui o ka hāʻawiʻana o 3-o-tetradormetl-l-sericayme a me ka hoʻohanaʻana i ka mea i hoʻopaʻaʻia i ka crainet. Nagao lāuaʻo KitO i aʻo i ka O-Acylation o L-Serines Acylation o ka L-TReronine a hoʻokuʻuʻia.
Ua kākoʻoʻia nā mea noiʻi nui i ka hoʻohanaʻana i nā mea waiwai a me nā manawa hou i loaʻa i ka synthesis o nā kumukūʻai kūpono. Soo et al. Ua'ōleloʻo ia ka hoʻomākaukauʻana o ka hoʻomākaukauʻana i nā mea hana maikaʻi o ka hanaʻana i nā mea hana maikaʻi loa me ka immobilinized lipoeenzme. ʻAʻole lākou i manaʻo eʻoi aku ka nui o nā huahana o nā huahana eʻoi aku ka maikaʻi o ka manawa e hoʻopau i ka hopena (6 mau lā). Gorea et al. noiʻi i ka synthesis a me nā hana ākea o ka chiral n-pacmini, slineline, licyeline Ua weheweheʻo Pang a me Chu i kā Ioio Acinoms A me nā maʻiʻo Meno hoʻomanakaʻi a me nā Colnomerxesʻo Aila'Alika i pili i ka hoʻonāʻana i ka maʻi.
Ua hōʻikeʻo Canterauzene a me Gerreiro i ka Esterification o nā huiʻo Carborexic o Boc-Oh a me DICLOROSE 4B (Sepharose 4b). Ma kēia noiʻi,ʻo ka hopena o Boc-Ala-Oh me ka momona momona a hiki i nā 163% ka maikaʻi o Boc-Asp-Asp-Asp-asp 99.9%) i nā huahelu mai 58% a hiki i 76%, e hoʻopiliʻia ana e nā mea momona
5.2.2 Synthesis o Gemini-Orino Acido Acid / Peptide Carfants
ʻO nā mea hana amino Achini Acid-E pili ana i nā moina aʻelua mau molena i pili i ke poʻo-poʻo i loko o ke poʻo o ke poʻo. Aia he 2 hiki i nā mea hana no ka chemenzymatic synthesmatic o nā gemini-type amino Acid-Sych Octidants (kiʻi 6 a me 7). Ma ke kiʻi 6, 2 mau acid Acoid Drivatives e like me ka compound e like me ka hui spacer a laila ua hoʻokomoʻia nā huiʻo 2 mau hydrophobic. Ma ke Kākau 7, Ua pili pololeiʻia ka 2 pololei o ka 2 me ka pilina pili pololei e a pilipili i kahi huiʻo Biffunction Sucer.
Ka hoʻomohala muaʻana o ka enzyme-catalyzed synthesis o geminisis o geminimino acpids i hoʻopaʻaʻia e ka valivety et al. Yhimura et al. noiʻi i ka synthesis, adsorption a me ka hoʻohuiʻana o nā mea hana gemini amid amido Achini-Survini ma muli o ka Cystine a N-Alkyl Bromode. Ua hoʻohālikelikeʻia nā mea hana synthesized me nā mea pili monomericing. Faussino et al al. ua weheweheʻo ia i ka synthesis o nā monomer urea Ua hōʻikeʻia e like me ka haʻahaʻa o ka gmc o Gemini ma ka hoʻohālikelike Mnomer And Gemini.
ʻO ka synthesis o nā gemini a me ka hoʻohanaʻana i nā derivitatives ata a me ka spacer, hahaiʻia e ka hoʻokomoʻana o ka hui hydrophobic
ʻO Fig.7 synthesis o ka gemini aass e hoʻohana ana i ka spacer bucunction a me Aas
5.2.3 synthesis of glyceroipid acid acid / peptide nā mea kanu
ʻO Glyceropid amino Acid Acid / Peptide Garticants he papa hou o Lipid Amino a iʻole nā Chotspholitids a me nā Phospholipids a me nā Phospholiplids a me nā Phospholitid i keʻano o ka Gyercetrol Hoʻomaka ka synthesis o kēia mau mea hana me ka hoʻomākaukauʻana i nā mea e hoʻonui ai iā glycetrol e hoʻonui i nā marids a me ka heleʻana o kahi paila Acidic (e like me bf 3). Enzyme-catalyzed synthesis (me ka hoʻohanaʻana i nā hydrolases, nā pale a me nā lipases e like me nā catalysts) kahi koho maikaʻi loa (kiʻi 8).
Ua hōʻikeʻia ka syntome-catalyme Ua hōʻikeʻiaʻo Synthesis o ka Diacylglycetrolcetrolvering Everter mai Austyrricaine a me ka loiloi o kā lākou mea mālama kino.
ʻO Fig.
spacer: nh- (ch2)10-Nh: hoʻohuihui
spacer: nh-c6H4-Nh: coupoundb2
SPAcer: ch2-K2: coupoundb3
ʻO Fig.9 synthesis o nā ampiphiles symmetriles i loaʻa mai i tris (hydroxxymyl) aminomethane
5.2.4 Synthesis of Bola-Orino Acid / Peptide Stuffants
Loaʻa i nā AMODO ACID-BOID GOCH-TYPOPHIPLES i 2 AMINO ACODA E PILI ANA I KE KOLOHE ANA I KE KOLOHE ANA. Franceschi et al. i wehewehe i ka synthesis o nā bola-type amphiphiles me 2 amino acids (d- a iʻole l-alaline a iʻole l-henkin a iʻole he lōʻihi o ko lākou mau lōʻihi. Ke kūkākūkā nei lākou i ka synthesis a me ka hoʻohuiʻana o nā ampiphing bola-type me kahi'āpana Amino Achid i kahi hui a me ka waihoʻoluʻu. Hiki i nā Aminmon velcommon β-amino e hiki ke lilo i ke kīwīʻo Aminocid, he azidomoyyinmid, a me azt) i luna mai Azt (Kiʻi 9). ʻO ka synthesis o nā symmetrical bola-type amphichhiles i loaʻa mai i tris (hydroxymyl) aminomethane (tris) (Kiʻi 9).
06 Nā waiwai olakino
Ua kaulanaʻo ia e pili ana i nā mea hana amino amino e pili ana i nā mea hana (Aas) a me ka hana maikaʻi a me ka maikaʻi o ka hopena maikaʻi loa.
E pili ana i nā mea e pili ana i nā kumuwaiwai amino
6.1ʻO keʻano koʻikoʻi miclele (cmc)
ʻO kaʻike nuiʻana o Micfele kahi mea nui o nā mea nui o nā mea hana a me nā gevers he nui, e hoʻonui i ka nui o ka chc. ʻO nā mea hana e pili ana i nā Amino Amino Amine i nā mea i hoʻohālikelikeʻia i nā kumu cmc i hoʻohālikelikeʻia i nā mea hana maʻamau.
Ma o nā hui likeʻole o nā pūʻulu poʻo a me nā puʻupuʻu hydrophobid E hoʻohālikelike i nā Aila i kohoʻiaʻekolu Argini Ma kekahi haʻawina'ē aʻe,ʻo Singare a me Mhatre i loaʻa i ka CMC o nā mea kanu N-α-Ayyrriniinene e hoʻonui i ka helu o nā carbon carbon i ka helu
Yhimura et al. Ua noiʻi i ka CMC o CMC o Cysteine-Drivian Amid-Survini i ka lōʻihi o ka cmc
Faussino et al al. ua hōʻike i ka hoʻokumuʻana o nā micelles i huiʻia ma nā hopena kūpono o nā mea hana a anionic geminicants e pili ana ma cystine. Ua hoʻohālikelikeʻia nā mea Gemini Gemicants i nā mea hana pili i nā monomericing monomeric Ua hōʻikeʻia nā helu cmc o nāʻano lipid-ciactant i hōʻikeʻia ma lalo o nā mea o nā mea maʻemaʻe. Gemini Sitmicats a me 1,2-diertanoyl-sn-glyceryl-3-phosphocholinel-3-phosphochina
Ua noiʻo Shrestha lāuaʻo Araraki i ka hoʻokumuʻana o nā ciscoolastic worm-like me nā mea e pili ana i nā mea hana anionic-nontic I kēia noiʻi,ʻo n-doccyl glutamate ua loaʻa i kahi mahana o ke kraf Eia nō naʻe, i ka wā e pili ana i ka hanaʻana me ka m-lysine amino anidine, ua hoʻomakaʻia nā micsine a me ka hopena e like me ka wai hou ma 25 ° C.
6.2ʻO ka waiʻona maikaʻi
ʻO ka hopena wai maikaʻi maikaʻi loa o AAS ma muli o ke alo o nā kāpena co-nh. Hana kēia iā AAS i nā biodegradable a me ke kaiāulu ma mua o nā mea e pili ana i nā mea hana maʻamau. ʻOi aku ka maikaʻi o ka wai o ka wai n-acyl-l-glutamic iʻoi aku ka maikaʻi ma muli o kāna mau hui 2 mau hui. He maikaʻi loa kaʻona wai o CN
6.3 Krafft mahana a me Krafft Point
Hiki ke hoʻomaopopoʻo Krafft mahana e like me keʻano kūpono o nā mea i loaʻa i nā mea he nui e hoʻonui ai i keʻano o ka mahana. Loaʻa i nā mea hana a me nā mea hana aloha e hana ai i nā hydrad hydrates, hiki ke hoʻopau i ka wai. Ma kahi mahana kūikawā (ʻo ia ka mea i kapaʻiaʻo Krafft mahana), kahi hoʻonui nui a me ka hoʻonuiʻana i ka hopena o nā mea kanu. ʻO ka Krafft Point kahi o kahi mea nona ka inoa inoa inoa inoa inoaʻo Krafft ma cmc.
ʻIke pinepineʻia kēiaʻano soughbity i nā mea heʻeo'eneka e like me: e hoʻonuiʻia ana ka maʻalahi o ka moho. No ka hōʻoia pono i ka hopena piha, pono ia e hoʻomākaukau e hoʻomākaukau i nā hana hana ma luna o nā mahana ma luna o ka KRAFTT POSTE.
Ua aʻoʻia ka mahana o Krafft o AAS a hoʻohālikelikeʻia me nāʻano he nui o nā miclication ma mua syntheszedʻeono mauʻano likeʻole o nāʻano o ka n-hexadentl Aas a kūkā i ka pilina ma waena o ko lākou nohoʻana a me nā nohona Amino Amid Acid.
I nā hoʻokolohua, ua loaʻa i ka mahana o ka Krafft o N-Hexadentl a me ka hoʻohaʻahaʻaʻana i ka nui o nā nohona o Amino Acid. Ua hoʻopauʻia ia i kēlā me kēia manawaʻo Lalina a me nā'ōnaehana Phenylalanine,ʻoi aku ka ikaika o ka DL i keʻano o ka moteraction ma ka paʻakai.
Brito et al. hoʻoholo i ka mahana o ke Krafft oʻekolu mau papa o nā mea e pili ana i nā micoid acid acid-e pili ana i ka hoʻomehanaʻana i ka trifcoly ʻO ka heleʻana o nā bis-ʻelua mau pūlima a me ka unsaturation i kēia manawa i ka lōʻihi o nā ceriva-ciin ser-derivatives i alakaʻiʻia i kahi haʻahaʻa o Kraft. Ua hōʻikeʻiaʻo N-Dodecyl Glutamate e loaʻa i kahi mahana kiʻekiʻeʻo Kraft. Eia nō naʻe,ʻo kaʻaeʻana me ka pono amino antid amid l-lilsine i hopena i keʻano o nā micelles i ka hopena e like me nā wai hou e like me Newtonian e like me Newtonian e like me Newtonom
6.4 ka'ā'ī
ʻO ka hanaʻana o ka maka o nā mea hana e pili ana i ka lōʻihi o ka kaulahao o ka hapa hydrophobic. Zhang et al. hoʻoholo i ka paleʻana o ka pā o ka sodium cocoyl gollacinate e keʻano o Wilhelmy e keʻano o Wilhelmy Yhimura et al. hoʻoholo i ka paleʻana o ka papa o 2c n cys type Amino Acid ma luna o 2c n cys-cycter becter-off. Ua loaʻa iā ia ka neʻeʻana o ka maka o ka maka ma ka cmc i ka hoʻonuiʻana i ka lōʻihi o ke kaulahao.
ʻO ka hopena o ka cac1 2 ma ka nānāʻana o ka helehelena o nā mea i hanaʻia e pili ana iā Acid Agid Acid. Ma kēia mau noiʻi, ua hoʻohuiʻiaʻo Cac1 2 i nā hopena kūpono o nā mea e aeʻo Amino Amino Amid-Tychna 2, a me C12 Glouna 2). Ua hoʻohālikelikeʻia nā kumu proteau ma hope o ka hoʻohālikelikeʻana o Cmc a uaʻikeʻia ua emi ka maka o ke aniani ma ka haʻahaʻa o nā cec1 2. ʻO kēia ma muli o ka hopena o ka calcum i ka hoʻonohonohoʻana i ka hoʻonohonohoʻana o ka mea e pili ana i ka wai-wai. ʻO nā'āpana o nā Salts o nā Salts o N-Dodecylaminhiate a me N-Dodecylashtate, ma kaʻaoʻao'ē aʻe e kū pono ana i ka 10 mmol-l -1 cac1 2. Ma luna o 10 momol-l -1 No ka palupulu o ka discotium o ka n-dodinesl glutamate, hoʻohui hou o ka cac1 2 i hopena i ka hoʻonui nuiʻana i ka coc1 2
No ka hoʻoholoʻana i nā kinipōpō Adsorption o nā gemini i loko o keʻano o ka gemini i ka waiʻahu wai, ua hoʻoholo ka umauma paepae nui. Ua hōʻike nā hopena i nā manawa hoʻokolohua lōʻihi loa,ʻaʻole i loli ka helu 2c 12 cyenamic. ʻO ka emiʻana o ka emiʻana o ka nui o ka wīwī o ka mana o ka mana i hilinaʻi wale ma kaʻike, ka lōʻihi o kaʻalā o ka hydrophobic, a me ka nui o ka hydrophobic nā makai. Ka hoʻonuiʻana i kaʻikeʻana o nā mea hana, e hōʻemi ana i ka lōʻihi kaulahao i ka lōʻihi o ke kaulahao e like me ka nui o nā kaulahao i loaʻa i kahi hala wikiwiki. Loaʻa nā hualoa no nā mea kiʻekiʻe kiʻekiʻe o C N CW (N = 8 a 12) uaʻikeʻia e ka 'cmc i hanaʻia e ke ala Wilhelm.
Ma kekahi haʻawina'ē aʻe, mau kaheʻe nui o Sodium Dilanauryl, ua hoʻoholoʻia ka papaʻo Wilhelnis e ka huiʻana o ka lehulehu. Ua noiʻi houʻia ka hopena o nā mea i hoʻopiʻiʻia e nā mea hana'ē aʻe e nāʻano'ē aʻe e like me nāʻano'ē aʻe. ʻO ka hoʻohuiʻana o Mercaptothanol i 0.1 mmol-l -1sdlc spect i alakaʻi i kahi piʻi wikiwiki mai ka nui o ka hōʻailonaʻana mai 34 mn-m -1. Mai ka mea hiki i ka naclo hiki i nā mea e hoʻopili ai i nā mea i hoʻopiliʻia i ka sdlc i nā hui acid acid acid,ʻaʻohe mea i hoʻopiliʻia i ka wā o Noml-L -1). Ua hōʻikeʻia nā huapalapala uila a me nā huapalapala uila uila. Ua loaʻa i ka maka o SDLC i loaʻa i ka hoʻonuiʻia mai nā 34 mn-m -1 a 60 m -1 ma luna o 20 min.
6.5 mau hoʻonohonoho kino kūpono
I loko o nāʻano ola ola, ua aʻoʻia kekahi mau pūʻulu i nā mea waiwai o nā huiʻana o nā mea kūʻai aku.
6.6ʻO nā waiwai Aggregation
Hoʻohana pinepineʻiaʻo Dynamic Light Spelling e hoʻoholo ai i nā waiwai o Amino Acid e pili ana i ka cmc. Ua hanaʻia nā aggregeates e c n cys a me 2cn cys i nui a loaʻa i kahi māhele ākea ākea i hoʻohālikelikeʻia i nā mea'ē aʻe. ʻO nā mea āpau a pau wale nō ma mua o 2c 12 cys i hana maʻamau i nā makahiki he 10 nm. Ua nui ka nui o nā micelle o nā mea gemini iʻoi aku ka nui ma mua o nā mea o ko lākou mau monomeric counterports. Ka hoʻonuiʻana i ka lōʻihi o ka windrocarbon wind i alakaʻi i ka hoʻonuiʻana i ka nui micelle. Ohta et al. i wehewehe i nā waiwai o nāʻano heʻekolu mau stereoitisersʻekolu o nā n-dodecyl-phenyl-phenyl-phenyl-phenyl-phenyl-phenyl-phesetith-phesesatith Iwahashi et al. noiʻiʻia e ka dichirism circularist 1,2-DICLOLOOROORETHANE) me nā waiwai i hoʻopiliʻia e nā mea waiwai i noiʻiʻia e ka dichirism circularism
6.7 Hoʻohui Pūnaewele
ʻO ka hoʻolahaʻana o ka interfacial o nā mea hana amino amino amino a me kāna hoʻohālikelikeʻana me kāna counterdal counterpart kekahi o nā kuhikuhi noiʻi. ʻO ka laʻana, nā waiwai adsorpial e pili ana i nā hana o ka dodeccyl esters of amanitic amitic a me nā lep a me ka lep. Ua hōʻike nā hopena eʻae a hoʻokuʻu iā Lep i nā wahi haʻahaʻa haʻahaʻa haʻahaʻa ma ka wai wai-wai a ma ka wai wai.
Nā Bordes et al. ua noiʻi i ka hopena o keʻano a me ka adsorption ma keʻano o ka wai-wai i waena o nā mea heʻekolu, a me nā hola 1, 2, 2, a me nā 2, 2, 2, 2, a me 3, 2, 2, a me ka 3, 2, 2, a me nā 2, 2, 2, a me nā hola 1, 2, 2 Wahi a kēia hōʻike,ʻo ka cmc o nā mea hana dicarbolyeded he 4-5 mau manawa kiʻekiʻe ma mua o ka paʻakaiʻo Molcachine Ua hōʻikeʻia kēia i ka hoʻokumuʻana o nā mea paʻa hydrogen ma waena o nā mea i hoʻopaʻaʻia ma waena o nā mea e pili ana i nā hui a me nā mea e pili ana i nā hui ameti.
6.8ʻO keʻano hana
Ua nānāʻiaʻo Isotropic i nā wahi cubic cubic i nānāʻia no nā mea hana ma nā mea kiʻekiʻe kiʻekiʻe. Nā molena nā luna he nui me nā pūʻulu poʻo nui nui loa e hana i nā makahiki he nui o ka curvature maikaʻi. marques et al. E aʻo i ka hana o ka hana o ka 12lys12 / 12ser a me 8ss8 / 16ser system i waena o nā mea he 8lys8 / 16ser8 / 16ser8 / 16ser. ʻO ka'āina'āina). Pono e hoʻomaopopoʻia no ka'āinaʻo Scolicle o ka waihona 12lys12 / 12ser,ʻo Vesicles e pili ana i nā micleles
Nā momi catanicic o ka lysine- a me nā mea hana o Serine-Serine-Service
6.9 emulisfying hiki
Koichi et al. ua nānā i ka hikiʻana i ka hiki, ke kūpaʻa interfacial, paleʻole, a me ka vacosityl-2-herdiexyprotate, l -l-arminemate, a me nā Aatama. I ka hoʻohālikelikeʻana me nā mea hana synthetic (ko lākou mau kumuwaiwai nonhosic
Baczko et al. ʻO nā mea hoʻonaninani noverotic inionic acid acid amid a me kā lākou kūpono e like me ka claral or chiral spectroscopy colvents. ʻO kahi papa o ka sulfonate e pili ana i ka amphiphililic l-phe a iʻole l-ala drivatives me nāʻano he nui Wu et al. syntheszed sodium salts o n-momona acayl Aas aua noiʻi i ko lākou hikiʻana i ka hopena o ka wai i loko o ka wai wai-wai, a ua hōʻikeʻia nā hopena i kēia mau hana e like me keʻano o ka aila.
6.10 mau holomua ma synthesis a me ka hana
Hiki ke hoʻomaopopoʻia ka paleʻana o ka wai paʻakikī e like me ka hiki ke kū'ē i ka heleʻana i ka wai o ka calcium He mea maikaʻi loa nā mea hana me nā pale o ka wai paʻakikī no nā hana kūpono a me nā huahana mālama pilikino. Hiki ke loiloiʻia ka paleʻana i ka wai i ka heluʻana i ka loli i ka palena a me ka hana o ka hana o ka mea e hiki mai ana i keʻano o ka calcigant
ʻO kahi ala'ē aʻe e loiloi ai i ka paleʻana i ka wai paʻakikī e helu i ka pakeneka a iʻole nā grama i nā mea e pono ai ka chicium i hanaʻia mai ka wai. I nā wahi me nā wai paʻakikī kiʻekiʻe, kiʻekiʻe kiʻekiʻe o ka calcium a me nā magnesium i hiki i nā makemake a me nā mea mele ke hana i kekahi mau noi kūpono. Hoʻohana pinepineʻia ka sodium i loko o ke counter i loko o kahi mea i loko o kahi mea hana sitnthetic anonic. ʻOiai ke kauʻiaʻana o ka calcium calcium i loko o nā molenaʻelua, e kumu ana i ka mea e pono ai ka mea e hiki ai i ka hoʻonāʻana o ka hoʻoholoʻana.
Ua hōʻikeʻia ka hoʻopaʻaʻana o ka wai paʻakikī o Aas i hōʻikeʻia ai ka pale wai a me ka nui o ka wai. ʻO ke kauoha o ka acid a me ka hōʻeha o ka wai ka nui c 12 glycinate <c 12 aspartate <c 12 glutamate. Ke hoʻohālikelike nei i ka paʻa o ka DICARBOXYED ADID a me nā mea e pono ai nā mea i hanaʻia a me nāʻano o ka hope o ka onikau. Ua hōʻike aku ka DICARBOXYBY N-Alkyl Amino Agids i ka hopena chelating i ka heleʻana o nā callium o nā callium over, a c 12 aspartate i hanaʻia i ke kaikamahine keʻokeʻo. C 12 Glutamate i hōʻike i ka hana kiʻekiʻe ma luna o ka hana kiʻekiʻe ma ke kiʻekiʻe o ka cap 2+ a manaʻoʻia e hoʻohanaʻia i loko o keʻano o ke kai.
6.11 dispersility
E pili ana i nā mea hoʻowahāwahā i ka hiki ke pale i ka mea hana e pale ai i ka coalescecence a me ka sedimenttion o ka mea e pili ana i ka hopena.ʻO ka mea kūʻai aku he waiwai nui o nā mea kanu e kūpono ai iā lākou no ka hoʻohanaʻana i nā mea hoʻohana, nā cosmetices a me nā lāʻau lapaʻau.Pono kahi mea hoʻolaha i kahi mea nui, eter, eter
ʻO ka maʻamau,ʻo Aniionic e like me Alkanolamimido sulfates a me Amphoteric e like me AmicosuLuTice e like me nā Amidosully
Nui nā hana noiʻi he nui i hoʻoholo ai i kaʻaeʻana o nā AAS, kahi eʻikeʻia aiʻo N-Lauroyl Losine me ka wai a me ka paʻakikī e hoʻohana no ka wai a me ka paʻakikī e hoʻohana no nā hana cosmeticI loko o kēiaʻano, n-acyl-subsititted subsitit i nā amino ecids amio superb i loaʻa a hoʻohanaʻia i kaʻoihana cosmetic e hoʻomaikaʻi ai i nāʻano hana.
07 i pili
Nā mea hana maʻamau,ʻoi aku ka nui o nā mea kanu cantic, he mea nui loa i nā mea momona aquatic. ʻO kā lākou moʻomeheu e pili ana i ka phenomenon o ka adsorption-iron interraction o nā mea hana ma ka wai wai-wai. Ke hoʻemiʻana i nā cmc o nā mea kanu e alakaʻi pinepine i nā hoʻolahaʻana o ka interporpial ʻO ka hoʻonuiʻana i ka lōʻihi o ka lōʻihi o ke kaulahao hydrophobic o nā mea e alakaʻi i ka hoʻonuiʻana i nā mea kanu.ʻO ka hapa nui o AAS he haʻahaʻa a iʻole nā meaʻonaʻole i nā kānaka a me ke kaiapuniUa hōʻike nui nā mea noiʻi he nui a me nā meaʻole amino Acino Acin a me ka hoʻonāukiukiʻole i kaʻili. ʻIkeʻia nā mea hana o Argience
Brito et al. aʻo i nā mea lapaʻau a me nā mea hoʻonaninani o nā agion amino amidian a me ko lākou mau mea e pili ana i nā scatic (tyr). ʻO kā lākou mau virtics citanic casic
Rosa et al. noiʻiʻia i ka hoʻopaʻaʻana (hui) o ka DNA i nā Veid Amido Amid-E pili ana i nā Vatic Vatic. ʻAʻole like me nā mea maʻamau canticnal maʻamau, eʻike pinepineʻiaʻo ia e like me ka mea e like me ka launaʻana o ka cananic acico Acin ACIDIC ACO-DOXX. Hoʻokumuʻia ka cicatic asas ma luna o ka arginine, nā mea i hoʻopiliʻia e pili ana i nā vestics stable i hui pūʻia me kekahi mau mea hana anionic. Ua hōʻikeʻiaʻo Amino Achion Achion Inhibors E hui koke ana kēia mau mea hele me ka maʻemaʻe kiʻekiʻe Ua hōʻikeʻia kekahi mau haʻawina i ka Sulfur
I kahi noiʻi hou, pertinelli et al. Ua hōʻike i kahi mea maikaʻi loa o ka loaʻaʻana o Rhamnolipids i hoʻohālikelikeʻia i nā mea hana maʻamau. ʻIkeʻia nā rhamnolipipids e hana e like me ka hoʻonuiʻana o ka permebility. Ua hōʻike pū lākou i ka hopena o Rhamnolipids ma keʻano o ka epithelial o ka epithelial o nā lāʻau lapaʻau macromolecular.
08ʻO ka hana Antimicrobial
Hiki ke loiloiʻia ka hana Antimicrobial o nā mea e pili ana i kaʻike liʻiliʻi loa. Ua aʻoʻia ka hana antimicrobial o nā mea hana o Arnimine Ua loaʻa i nā mea maikaʻi o Gram-maikaʻiʻole e loaʻa hou aku i nā mea eʻoi aku i nā mea e pili ana i ka argini Ua hoʻonui pinepineʻia ka hana Antimicrobial i ka heleʻana mai o ka heleʻana o ka hydroxyl, cyclopropopane a iʻole paʻaʻole i loko o nā kaulahao acel. Casilllo et al al. hōʻikeʻia ka lōʻihi o nā kaulahao Acyl a me ka uku kūpono e hoʻoholo ai i ka uku HLB (hydrophilic ʻO ka papa inoaʻo Nα-Ayylarnine Mithyl ester he mau papa nui he nui o nā mea kanu cantic me nā hana ākea a me ka haʻahaʻa a he haʻahaʻa paha. Nā haʻawina ma keʻano o ka launaʻana o nā mea e pili ana i nā mea e pili ana i ka 1,2-dipaltinoyl-3-phospornoyl-3-phospornoyl-3-phostarronesl-3-dateradems i mua o nā mea ola Hōʻikeʻia ua hōʻikeʻia kēia papa o nā mea kanu i nā hopena antimicrobial i hōʻike i nā hopena i hōʻikeʻia e loaʻa nā hana antibactacter.
09ʻO nā waiwai Rheological
ʻO nā waiwai RHEOBOLIBIES O nā mea hana e pāʻani ai i kahi hana koʻikoʻi nui i ka hoʻoholoʻana a me ka wānanaʻana i nā huahana Ua alakaʻiʻia nā haʻawina he nui e kūkākūkā i ka pilina ma waena o Viscoolasticity o Amino Acino Acin Acin Acid a me CMC.
10 mau noi i loko o kaʻoihana cosmetic
Hoʻohanaʻiaʻo AAS ma keʻano o nā huahana mālama pilikino.Ua loaʻaʻo Potassium N-Cocoyl Glycinate eʻoluʻolu ma kaʻili a hoʻohanaʻia ma ka hoʻomaʻemaʻeʻana i ka mea hoʻomaʻemaʻe a me ka makeup. N-ACYL-L-GLutamic AcID he mau pūʻulu carboxylʻelua mau pūʻulu crabobyl, e lilo ai i ka wai nui. I waena o kēia mau anas, AAS e pili ana i ka 12 momona apu he nui ka hoʻomaʻemaʻeʻiaʻana e wehe i ka palaka a me ka makeup. Hoʻohanaʻiaʻo AAS me kahi CHIN i hoʻohanaʻia e like me nā emalsifiers ma nā huahana mālama kino, a me n-laryl i kapaʻia i kaʻano o nā huahana mālama kino. ʻO nā AASL e pili ana i nā AAS i hoʻohanaʻia ma nā niho niho i hana maikaʻiʻia e nā mea e like me ka soap a me nā enzyme-ikaika ikaika.
I nā makahiki i hala iho nei, ke kohoʻana o nā mea kanu no nā cosmetics ʻIke maopopo loa nā mea kūʻai aku o kēia mau huahana i ka hoʻonāukiukiʻana i ka hoʻonāukiuki, nā mea waiwai a me nā kumu kūlohelohe.
I kēia lā, hoʻohanaʻiaʻo AAS e hana i nā shampos he nui, nā manu lauoho a me nāʻauʻauʻauʻau ma muli o ko lākou mau mea hana maʻamau a me nā huahana mālama pilikino.ʻO nā mea kūʻai aku e pili ana i nā mea waiwai e pono ai no nā huahana pono no nā huahana mālama pilikino. Loaʻa i kekahi mau kiʻi kiʻi kiʻi kiʻi kiʻi kiʻi,ʻoiai he mau mea'ē aʻe e loaʻa ai nā mea kūpono maikaʻi.
He mea nui nā amino e hōʻike pono ana i nā mea misiturizing i nā mea i loko o ka stratum corneum. I ka makeʻana o nā cell cells epienmal, lilo lākou i'āpana o ka stratum corneum a me nā protracellular i hoʻopiliʻia i nā maʻi amino. ʻO kēia mau amino e laweʻia ana i nā corneum stratum, kahi e hāʻawi ai lākou i nā momona momona a iʻole ka hoʻomaikaʻiʻana i ka elader i ka maka o kaʻili o kaʻili. Ma kahi o 50% o ka hana kūlohelohe kūlohelohe o kaʻili i loko o kaʻili e hoʻopiliʻia ana i nā amino Amino Acidids a me Pyrrorrodone.
Collegen,ʻo ka mea hana maʻamau, aia nō nā mea amono maʻamau e hoʻomau i kaʻili.ʻO nā pilikiaʻili e like me ka paʻakikī a me ka paʻakikī e pili ana i ka hapa nui i ka hapa nui o nā amino amino. Ua hōʻikeʻia kekahi haʻawina e pili ana i kahi Amino Amid Acoid me kahiʻili i hukiʻia, a hoʻi mai nā wahi i loaʻa i ko lākou'āina maʻamau me ka liloʻole i nā wahi maʻamau.
Ua loaʻa nā Amino Acids i mea nui loa e pono ai i ka mālamaʻana i nāʻoki i hōʻinoʻia.ʻO ka maloʻo maloʻo, e hōʻike ana i ka lauoho liʻiliʻiʻole e hōʻike i kahi hōʻemi i ka hoʻopiliʻana o nā amino Amino i kahi kiko'ī i hōʻehaʻia. ʻO nā amino e hōʻoia i ka hiki ke komo i ka culecle i loko o ka shaft lauoho a me ka hōʻiliʻiliʻana mai kaʻili.ʻO kēia hiki i ka hanaʻana a Adino hana i nā mea hana nui iā lākou ma Samapoos, nā lauoho lauoho, lauoho lauoho amane, a me ke alo o na lauoho lauoho.
ʻO 11 nā noi i nā mea kanu i kēlā me kēia lā
I kēia manawa, aia kahi noi e ulu ana no ka hana amino amid ided-formors formumentʻIkeʻiaʻo Aas e loaʻa i ka hoʻomaʻemaʻe hoʻomaʻemaʻe maikaʻi, e hōʻeha ana i nā mea pono a me nā sobric no ka hale e hana ai no ka hale no ka hale hana a me nā mea hana'ē aʻe.Ua hōʻikeʻia kahi aspartic Acad-Doundic ATAS AAS e lilo i mea hana maikaʻi loa me ka nānāʻana i nā waiwai chelating. ʻO ka hoʻohanaʻana i nā mea kanu e pili ana i nā mea nona nā N-Alkyl-β-aminothoyhoxy Entids i loaʻa e hōʻemi i ka huhūʻili. ʻO kahi mea e hoʻokaʻawale ai kahi wai wai e pili ana i ka N-Cocoyl-β-aminopropipionate i hōʻikeʻia e lilo i mea kūpono no nā wahi aila. Aia kahi mea he AcidocarbOxylical, C 14 Chohch 2 NHCH 2 CONA, ENGOTES-3-AMACOHOLOHE.
ʻO ka hoʻomākaukauʻana o nā hana hoʻohālikelike e pili ana i nā n- (N'-Long-Long-Chain Actyl-β Alanyl) Hoʻokumuʻo Kao i kahi hana e pili ana i ka mea e pili ana i n-acyl-1 -n-hydroxy-β
Ua hoʻohanaʻo The Jearman Ajinomoto i nā haʻahaʻa haʻahaʻa haʻahaʻa a maʻalahi hoʻi i nā AAS e pili ana i nā shampos a me nā cosmecis a me nā cosmine ʻO ka hiki ke hoʻonui i nā mea hoʻohui i loko o nāʻano hana i hanaʻia e wehe i ka loaʻaʻana o ka fulti i hōʻikeʻia. N-Actyl Aas i loaʻa mai Glutamic Achutamic AcID, Malinlglycine,ʻo Mizey a me'Aspartic Acid Effents cold i nā hoʻonā maikaʻi loa. ʻAʻole e hoʻonui i kēia mau mea hana i ka viscosity i nā mea āpau,ʻoiai ma nā haʻahaʻa haʻahaʻa, a hiki ke maʻalahi maʻalahi i ka pauʻana o ka hale kūʻai home.
Post Time: Jun-09-2022